ZSM 12 chemical formula: Al6SinP6-nO24]-CHA, 0.8
Description
The structural properties of two series of high silicon aluminum ratio ZSM-12 zeolites synthesized using methyltriethylammonium iodide (MTEA) and tetraethylammonium iodide (TEA) as template agents The XRD results indicate that due to different template agents, the two series of ZSM-12 zeolites exhibit significant differences. As the silicon aluminum ratio increases, the decrease is in the T located in the main pore channel_ 1-T_ Skeleton aluminum at position 4. Also using NH_ The surface acidity properties of ZSM-12 zeolites from MTEA and TEA series were systematically studied using two methods, 8-TPD and pyridine-IR-TPD; The catalytic performance of the molecular sieve was studied by cracking isopropylbenzene, alkylating toluene with methanol, and isomerizing xylene.
Specification
Items |
Unit |
Data |
SiO2/Al2O3 |
mol/mol |
40-200 |
Na2O Content |
wt% |
0.04 |
Crystal Size |
μm |
0.2-0.4 |
BET Surface Area |
m2/g |
>400 |
Pore Size |
nm |
0.6 |
Bulk density |
Kg/m³ |
600 |
X-ray Crystallinity |
% |
95 |
Pore Capacity |
ml/g |
>0.3 |
Lattice constant (nm) |
Å |
|
Ignition Loss (550℃ 3h) |
wt % |
<8 |
Water Adsorption at 50% EH and 20FC |
wt % |
5 |
Applications
ZSM-12 is used in various reaction processes such as cracking, hydrocracking, isomerization, alkylation, polymerization, reforming, dehydration, etc.
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